Soft Crystal Chemiluminescence Systems Using Organic Peroxides

Crystal Growth of Organic Soft Materials in Template-controlling Systems

Crystallization phenomena of organic soft materials occurring in template-controlling systems such as emulsions, vesicles, micelles and air-water interfaces have been discussed by reviewing recent work. Long-chain molecular crystals and amino acids were chosen as the model substances of the organic soft materials which are key materials in food, pharmaceutical, nuetraceutical, cosmetic, and oth...

Synthesis of unstable cyclic peroxides for chemiluminescence studies

Peróxidos cíclicos de quatro membros são intermediários de alta energia importantes em diversas transformações quimi e bioluminescentes. Especificamente, a-peroxilactonas (1,2-dioxetanonas) têm sido consideradas sistemas modelo para a eficiente bioluminescência do vaga-lume. Contudo, a preparação deste tipo de compostos altamente instáveis é extremamente difícil e, por isso, apenas alguns pouco...

Organic Peroxides in Radical Synthesis Reactions

Rearrangements of organic peroxides and related processes

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O-O-b...

The Chemiluminescence of Organic Compounds

The chemiluminescence of organic compounds in solution is briefly surveyed with some emphasis on the mechanisms which result in relatively efficient population of an excited state of a product molecule. This is done in terms of the relation = x 'E 1F with particular reference to peroxide compositions. iNTRODUCTION The study of chemiluminescence mechanism in a persistent and systematic fashion i...